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| 巯嘌呤与铜的配合物的电化学研究 |
| A Study on the Polarography Adsorptive Waves of 6-Mercaptopurine with Copper(Ⅱ) Complex |
| 投稿时间：2004-08-27 修订日期：2004-11-22 |
| DOI： |
| 中文关键词: 6-巯基嘌呤 铜 极谱法 配合物吸附波 |
| 英文关键词:6-mercaptopurine copper(Ⅱ) polarography adsorptive wave of complex |
| 基金项目:广东省教育厅自然科学研究项目0164. |
| 作者 | 单位 | | 任乃林 | 韩山师范学院, 化学系, 广东, 潮州, 521041 | | 陈淑芝 | 韩山师范学院, 化学系, 广东, 潮州, 521041 | | 李红 | 韩山师范学院, 化学系, 广东, 潮州, 521041 |
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| 中文摘要: |
| 在0.1 mol/L的B-R底液(pH=4)中,用单扫描示波极谱法可以得到一个灵敏的6-巯基嘌呤与二价铜离子配合物的导数还原峰,其峰电位为-0.40 V(vs.SCE),其二阶导数波高与6-巯基嘌呤溶液在4×10-7~1×10-5mol/L浓度范围内呈线性关系,检测限为3×10-8 mol/L.该法可用于药物中6-巯基嘌呤的测定,平均回收率为98.7%.对6 MP Cu2+在汞电极上的电化学行为特别是对其吸附性能进行了探讨. |
| 英文摘要: |
| A sensitive reduction peak of 6-mercaptopurine with copper(Ⅱ) complex was found by single-sweep oscillopolarograph in 0.10 mol/L Britton-Robinson medium,The peak potential was at 0.41 V (vs.SCE), The height of second-order derivative wave was linear with the concentration of 6-mercaptopurine over the range of 4×10-7 to 1×10-5 mol/L and the detection limit is 3×10-8 mol/L. The method was developed for the determination of 6-mercaptopurine in medicine and the average recovery was 98.7%. The electrochemical behavious of 6-mercaptopurine with copper(Ⅱ) complex at Hg electrode and its adsorptive properties were also explored. |
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