近年物理化学滴定进展

Recent Advance on Physico-chemical Titration

中文关键词:  容量(滴定)分析  物理化学滴定  光学滴定  电滴定  量热滴定

英文关键词:Volumetric(titrimetric)analysis  Physico-chemical titration  Optical titration  Electrometri titration

中文摘要:

      评述了近五年国内外物理化学滴定(用作图确定终点)的新进展,内容包括:(1)光学滴定(含光度、荧光、磷光、化学发光滴定);(2)电滴定(含电位、电导、电流、库仑滴定);(3)量热滴定。每类滴定均再按滴定用介质分为水介质和非水介质滴定,按滴定反应分为酸-碱、氧化-还原、络合、沉淀滴定,按滴定方式分为直接滴定、代滴、回滴。引用文献106篇。

英文摘要:

      Advance on physico-chemical titrations(i.e.detection of the end-point by plotting)in red 5 year is reviewed.It contains1)optical titrantions(including photometric,fluorometric,phosphorometric and chemiluminescent titrations),2)elctrometric(including potentiometric,conductometric, amperometric and coulometric titrationsand 3)calorimetric titiration:(1)each of them is subdivided into aqueous and nonaqueous titrations according to the media used for the titration,(2)acid-base,redox, precipitation and complexation titrations according to the reaction included and(3)direct,replacement and back titrations according to the titraton models.106 reference are cited.